Characterization by NMR of Ozonized methyl linoleate
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چکیده
منابع مشابه
Characterization by NMR of Ozonized Methyl Linoleate
No presente estudo o linoleato de metila ozonizado com índice de peróxidos de 1.800 mmol-equiv. kg foi caracterizado quimicamente. Os efeitos do ozônio sobre o linoleato de metila produz hidroperóxidos, ozonideos e aldeídos, os quais foram identificados por técnicas de ressonância magnética nuclear de H e C, monoe bidimensional. O linoleato de metila padrão e o linoleato de metila ozonizado mos...
متن کاملMetabolism of monoepoxides of methyl linoleate: bioactivation and detoxification.
Leukotoxin (ltx) and isoleukotoxin (iltx) methyl esters, are metabolites of methyl linoleic acid, an essential fatty acid. They have been associated with acute respiratory distress syndrome. The observed toxicity of ltx and iltx is, in fact, due to the metabolism of the epoxides to their corresponding diols by soluble epoxide hydrolase (sEH). Herein, we demonstrate that ltx/iltx are toxic in a ...
متن کاملDepression of phagocytic activity of human polymorphonuclear leukocytes by methyl linoleate hydroperoxides.
Methyl linoleate hydroperoxides (MLHPO), a model for lipid hydroperoxides, decreased fungicidal activity of human polymorphonuclear leukocytes (PMN) for fungi of Candida albicans. When PMN was cultured with MLHPO, phagocytosis to fungi was depressed. Degree of the depression was dependent on the concentration of MLHPO and the treatment time with MLHPO. These findings indicate that phagocytic ac...
متن کاملInhibition of oxidation of methyl linoleate in solution by vitamin E and vitamin C.
The oxidation of methyl linoleate in solution initiated with azo compounds has been studied in the absence and presence of vitamin E and vitamin C. Both vitamin E and vitamin C acted as a chain-breaking antioxidant and they suppressed the oxidation and produced an induction period. The inhibition rate constant for the scavenging of peroxy radical was calculated at 37 degrees C as kinh = 5.1 X 1...
متن کاملComparative Study of Ozonized Olive Oil and Ozonized Sunflower Oil
Neste estudo, óleos de oliva e girassol ozonizados foram comparados química e microbilogicamente. Estes óleos foram introduzidos em um reator com gás ozônio borbulhante, em banho-maria a temperatura ambiente, até solidificação. O teor de peróxido, de iodo e o grau de acidez foram determinados juntamente com a atividade antimicrobiana. Os efeitos da ozonização na composição dos ácidos graxos des...
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ژورنال
عنوان ژورنال: Journal of the Brazilian Chemical Society
سال: 2007
ISSN: 0103-5053
DOI: 10.1590/s0103-50532007000300003